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Before this: Atomic structure

Electron configuration

Electrons occupy energy levels (1, 2, 3 and so on) around the nucleus. Each level contains sublevels, and each sublevel has a fixed capacity.

SublevelOrbitalsMaximum electrons
s12
p36
d510

Electrons fill the lowest-energy sublevels first, in this order:

1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p

An electron configuration lists each sublevel with its electron count as a superscript. The superscripts add up to the total number of electrons.

Worked example: sodium, 11 electrons

Fill in order until 11 electrons are placed.

  • 1s holds 2 (2 so far)
  • 2s holds 2 (4 so far)
  • 2p holds 6 (10 so far)
  • 3s gets the last 1

1s2 2s2 2p6 3s1

Common mistake

Filling 3d before 4s. The 4s sublevel is slightly lower in energy, so it fills first. Potassium is 1s2 2s2 2p6 3s2 3p6 4s1, not 3d1.

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Watch Filling the orbitals in order
  1. Hydrogen's one electron goes in the lowest sublevel: 1s1.
  2. Helium fills it: 1s2. An orbital holds 2 electrons with opposite spins.
  3. Lithium's third electron starts the next sublevel: 1s2 2s1.
  4. In 2p the electrons spread out, one per orbital, before any pair up: 1s2 2s2 2p3.
  5. Oxygen's eighth electron has to pair up: 1s2 2s2 2p4.
  6. Sodium, with 11 electrons: 1s2 2s2 2p6 3s1.

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Explore Fill the orbitals

Slide through the elements to see electrons fill the orbitals in order.

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Practice

1. What is the electron configuration of oxygen (8 electrons)?

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2. What is the maximum number of electrons a p sublevel can hold?

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3. Which element has the configuration 1s2 2s2 2p6 3s2 3p5?

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4. Which sublevel fills immediately after 3p?

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