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Before this: Molarity

Dilution

Diluting a solution means adding solvent. The amount of solute stays the same, but it is spread through a larger volume, so the concentration drops.

Because the moles of solute do not change, and moles = M × V:

M1 × V1 = M2 × V2

The 1 values describe the concentrated starting solution and the 2 values describe the diluted one. The volumes can be in any unit as long as both use the same one.

Worked example: diluting an acid

What volume of 12.0 M HCl is needed to make 500 mL of 3.00 M HCl?

M1 × V1 = M2 × V2

12.0 M × V1 = 3.00 M × 500 mL

V1 = 1500 M·mL ÷ 12.0 M = 125 mL

Measure out 125 mL of the concentrated acid and add water until the total volume is 500 mL.

Common mistake

Reading V2 as the volume of water added. V2 is the final total volume. In the example, the water added is 500 - 125 = 375 mL.

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Watch How much stock solution to use
  1. The goal is 500 mL of 3.00 M HCl.
  2. The stock bottle is 12.0 M.
  3. The moles of HCl do not change, so M1 × V1 = M2 × V2. Solve for the stock volume: 125 mL.
  4. Add water up to the final volume. That takes 375 mL, not 500.

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Explore Dilute a solution

Add water and watch the concentration fall. The amount of solute does not change.

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Practice

1. 50.0 mL of 2.00 M NaCl is diluted to 200.0 mL. What is the new concentration?

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2. What volume of 6.00 M HCl is needed to make 300 mL of 1.00 M HCl?

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3. 25.0 mL of 4.00 M solution is diluted to 0.500 M. What is the final volume?

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4. When a solution is diluted, the number of moles of solute:

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