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Before this: Solutions and solubility, Converting between mass and moles

Molarity

Concentration tells how much solute is in a given amount of solution. The most common unit in chemistry is molarity (M).

molarity = moles of solute ÷ liters of solution, or M = n / V

A 1.0 M solution contains 1.0 mol of solute in every liter of solution. M is read as “molar” and means mol/L.

Worked example: find the molarity

0.50 mol of NaCl is dissolved to make 2.0 L of solution.

M = 0.50 mol ÷ 2.0 L = 0.25 M

Worked example: starting from grams

What is the molarity of 10.0 g of NaOH in 500 mL of solution?

Moles: 10.0 g ÷ 39.997 g/mol = 0.250 mol

Volume: 500 mL = 0.500 L

M = 0.250 mol ÷ 0.500 L = 0.500 M

Worked example: find the moles

How many moles of solute are in 0.250 L of a 2.00 M solution? Rearrange to n = M × V.

n = 2.00 mol/L × 0.250 L = 0.500 mol

Common mistake

Dividing by milliliters. Molarity uses liters. Also, the volume is that of the final solution, not the water you started with.

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Watch Molarity from grams
  1. Dissolve 10.0 g of NaOH.
  2. Convert to moles with the molar mass: 0.250 mol.
  3. The finished solution has a volume of 500 mL, which is 0.500 L.
  4. Moles divided by liters: 0.500 M.

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Change the amount of solute and the volume of solution.

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Practice

1. What is the molarity of a solution with 3.0 mol of solute in 1.5 L of solution?

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2. How many moles of HCl are in 0.500 L of a 0.200 M solution?

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3. What is the molarity of 58.44 g of NaCl dissolved to make 2.00 L of solution?

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4. What mass of NaOH is needed to make 250 mL of a 1.00 M solution?

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