Open chemistry graphContribute

Before this: The pH scale, Mole ratios in reactions

Neutralization and titration

An acid and a base react to form water and a salt, which is an ionic compound. This is neutralization.

acid + base → salt + water

HCl + NaOH → NaCl + H2O

The H+ from the acid and the OH− from the base combine into H2O. The leftover ions make up the salt.

A titration finds an unknown concentration. A solution of known concentration is added slowly to the unknown until the acid and base have exactly reacted. An indicator changes color at that point, called the endpoint.

At the endpoint, moles of H+ equal moles of OH−. For an acid and base that react 1 to 1:

Ma × Va = Mb × Vb

Worked example: a titration

25.0 mL of HCl is neutralized by 20.0 mL of 0.500 M NaOH. What is the concentration of the acid?

Ma × 25.0 mL = 0.500 M × 20.0 mL

Ma = 10.0 M·mL ÷ 25.0 mL = 0.400 M

Common mistake

Using the 1 to 1 formula when the ratio is different. H2SO4 releases two H+ per formula unit, so 1 mol of it neutralizes 2 mol of NaOH. Write the balanced equation and use its mole ratio.

0 human reviews0 AI reviewsHelp review it

Watch Acid plus base gives salt plus water
  1. Hydrochloric acid and sodium hydroxide react to form a salt and water.
  2. The acid's hydrogen and the hydrogen in the base's OH both end up in water: 2 hydrogen atoms.
  3. The ions left over, sodium and chloride, make the salt.
  4. It balances 1 to 1. That is why Ma × Va = Mb × Vb works for this acid and base.

0 human reviews0 AI reviews

Practice

1. What are the products of HNO3 + KOH?

0 human reviews0 AI reviews

2. 30.0 mL of HCl is neutralized by 15.0 mL of 0.200 M NaOH. What is the concentration of the HCl?

Answer recomputed0 human reviews0 AI reviews

3. What volume of 0.100 M NaOH neutralizes 25.0 mL of 0.200 M HCl?

Answer recomputed0 human reviews0 AI reviews

4. How many moles of NaOH are needed to neutralize 0.50 mol of H2SO4?

Answer recomputed0 human reviews0 AI reviews